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| Sir Donald Bailey (1901-1985) | Inventor of the famous World War II "Bailey Bridge" |
| Carol Barnes (1944-2008) | Newscaster |
| The Rt Hon David Blunkett MP | MP for Sheffield Brightside |
| Lee Child | Crime fiction novelist |
| Stephen Daldry, CBE | Director of films "Billy Elliott", "The Hours", and "The Reader". Artistic Director of Royal Court Theatre (1992-1998) |
| David Davies, OBE | Former Executive Director of the Football Association |
| Jessica Ennis | Great Britain Heptathlete - World Championship Gold Medalist 2009 |
| Martin Fry | Lead singer with 80s pop band ABC |
| Nicci Gerrard | Author (also writes as Nicci French) |
| Joanne Harris | Award winning author of books including "Chocolat" |
| Penny Hughes | Past-President, Coca-Cola Great Britain and Ireland |
| Eddie Izzard | Comedian, Actor |
| Amy Johnson (1903-1941) | Pioneering aviator of the 1930s |
| The Rt. Hon Lord Justice Maurice Kay | Lord Justice of Appeal |
| Sir Hans Kornberg | Master of Christ's College, Cambridge (1982- 1995), world-famous biochemist |
| Sir Harry Kroto | Nobel Prize for Chemistry 1996 |
| Vanessa Lawrence, CB | Director General of Ordnance Survey |
| Hilary Mantel, CBE, FRSL | Author and winner of the Man Booker Prize 2009 |
| Sir Peter Middleton | Chancellor of the University of Sheffield, Chairman of Camelot |
| John O'Leary | Former Editor of the Times Higher Education Supplement |
| Dame Anne Rafferty, DBE | Judge of the High Court of Justice |
| Sir Richard Roberts | Nobel Prize for Medicine and Physiology 1993 |
| Jack Rosenthal (1931-2004) | Playwright |
| Helen Sharman, OBE | Britain's first astronaut |
| Rachel Shelley | Star of Emmy nominated TV show 'The L Word' and of Oscar nominated movie 'Lagaan' |
| Linda Smith (1958-2006) | Comedienne |
| David Wetherall | Former Premiership footballer at Leeds United, Sheffield Wednesday and Bradford City |
| Howard Wilkinson | Former football manager at Leeds United and Sheffield Wednesday |
